In the vast world of chemistry, N-Phenylmaleimide (NPMI) stands out as a remarkable compound due to its diverse applications and unique properties. With its purity level reaching 99%, NPMI manufactured by Yangchen Tech has proven to be an invaluable addition to various industries, particularly as a heat-resistant modifier in resins such as ABS, PVC, photosensitive materials, and PMMA.
Chemical Structure
Chemical Formula
C10H7NO2
Molecular Weight
173.16
CAS No.
941-69-5
Packing Type
Paper bag (20 kg)
Improving Resin Properties
When used as a heat-resistant modifier in resins like ABS, PVC, photosensitive materials, and PMMA, NPMI significantly enhances the overall performance of these materials. By embedding NPMI into the polymer chains, it increases the internal rotational resistance of the chains, thereby improving the heat resistance of the resin.
The addition of just 1% NPMI as a comonomer to ABS can increase the heat distortion temperature by 2°C. This seemingly small increase can make a significant difference in the performance of the resin, especially in applications where high temperatures are encountered.
Moreover, when 10% NPMI is mixed with ABS, the heat-resistant temperature can reach 125-130°C. This remarkable improvement in heat resistance makes ABS resins modified with NPMI suitable for a wide range of applications that require high thermal stability.
Specification
Property
Limits
Results
Appearance
Yellow crystalline powder
Yellow crystalline powder
Purity %
>98
99.5
Melting Range ℃
>85
88~90
Other Benefits of NPMI
In addition to improving heat resistance, NPMI also enhances the impact resistance, hotmeltability, and processability of the resin. These properties are crucial for resins used in various industries, such as automotive, electronics, and construction.
N-Phenylmaleimide (NPMI) manufactured by Yangchen Tech is a versatile compound that has revolutionized the performance of resins in various industries. As a heat-resistant modifier, it significantly improves the heat resistance, impact resistance, hotmeltability, and processability of resins like ABS, PVC, photosensitive materials, and PMMA. The addition of NPMI to these resins can enhance their performance, making them suitable for a wider range of applications. With its unique properties and exceptional purity, NPMI continues to be a valuable addition to the chemical industry.
Why choose Yangchen Tech as your N-phenylmaleimide supplier?
1. Yangchen Tech, as a technology-based enterprise, has strong competitiveness and high reputation in the industry. This means that its product quality and service level are recognised by the market and the industry.
2. Yangchen Tech has extensive technical collaboration with a number of renowned colleges and institutions. This professional background and R&D strength provide a strong guarantee for its production of high quality N-phenylmaleimide.
3.N-Phenylmaleimide is a chemical product with high purity requirements. Yangchen Tech, with its strict quality management system and advanced production technology, is able to ensure the supply of N-Phenylmaleimide with up to 99% purity, which meets the needs of various high-end applications.
4. Yangchen Tech has accumulated rich experience and resources in the industry and has a stable supply chain. This means that it is able to ensure a stable supply of N-Phenylmaleimide, avoiding any shortage of raw materials or price fluctuations that may affect customers' normal production.
5. As a technology-based enterprise, Yangchen Tech focuses on communication and cooperation with customers and is able to provide personalised services and technical support. Whether it is product consulting, technical support or after-sales service, Yangchen Tech can provide customers with timely and professional solutions.
By choosing Yangchen Tech as your N-Phenylmaleimide supplier, you will be able to enjoy high quality products, stable supply chain, personalised service and competitive price. These advantages will help you improve production efficiency, reduce costs and enhance product competitiveness.
Unlocking the highest performance of engineering plastics with advanced thermal stabilization technology
Exploring Heat-Resistant ABS
Acrylonitrile-butadiene-styrene copolymer (ABS) is a widely used engineering plastic, prized for its exceptional toughness, rigidity, and ease of processing. However, standard ABS suffers from a significant limitation: its heat deflection temperature (HDT), typically ranging from 85°C to 95°C, restricting its use in high-temperature applications such as automotive parts, electronic housings, and industrial equipment. To overcome this shortcoming, manufacturers are constantly searching for effective thermal modifiers that balance performance, cost, and processing efficiency. Among these solutions, N-phenylmaleimide (N-PMI) has emerged as a leading additive for thermal enhancement of ABS. This article will explore the science behind N-PMI's effectiveness, aiming to provide high-performance N-PMI solutions for industries worldwide.
N-phenylmaleimide
N-phenylmaleimide
ABS Heat Resistant agent modifier
1. The Science Behind N-PMI: How It Improves ABS's Heat Resistance
N-PMI is a rigid cyclic monomer with a molecular structure consisting of 1,2-disubstituted vinyl groups embedded in a five-membered ring. When copolymerized with ABS or blended as an additive, it acts as a "molecular scaffold," restricting the mobility of the polymer chains. This restriction raises the glass transition temperature (Tg) of ABS, directly improving its heat resistance without compromising its mechanical integrity. Key mechanisms include:
- Enhanced Chain Rigidity: The phenyl and imide groups in N-PMI introduce steric hindrance, reducing chain rotation and improving thermal stability.
- Synergistic Copolymerization: N-PMI binds to the ABS polymer during the synthesis process, forming covalent bonds that stabilize the matrix and prevent thermal degradation. Research has shown that adding 10% N-PMI to ABS can produce ultra-high-heat-resistant ABS with an HDT of 125-130°C, a 30-40°C improvement over unmodified ABS.
2. Why N-PMI Outperforms Other Thermal Modifiers
While other additives (such as glass fiber, mineral fillers, or other imides) can improve heat resistance, they often sacrifice processability, impact strength, or surface finish. N-PMI offers the following unique advantages:
- Balanced Performance: It simultaneously enhances heat resistance, tensile strength, and melt processing.
- Low-Dosage Efficiency: Even a 1% addition can increase the HDT by 2°C, enabling precise calibration for cost-sensitive applications.
- Compatibility with Additives: N-PMI works synergistically with stabilizers, pigments, and flame retardants, making it an ideal choice for multifunctional composites. In contrast, fillers such as talc or silica can reduce toughness, while other thermal stabilizers typically require higher addition levels, increasing viscosity and complicating processing.
Basic Information
Property
Description
Chemical Name
N-Phenylmaleimide
Synonyms
NPMI, Monomaleimide
CAS Number
941-69-5
Purity
≥99%
Appearance
Pale yellow crystalline powder
Manufacturer
Shaanxi Yangchen New Material Technology Co., Ltd
Key Properties of N-Phenylmaleimide
Property
Description
Thermal Stability
Decomposition temp. >300°C
Glass Transition Temp. (Tg)
Significantly increases Tg of ABS and other resins
Compatibility
Compatible with styrenics (e.g. ABS, SAN), epoxy resins, and engineering plastics
Solubility
Dissolves in acetone, DMF, THF, etc.
3. Yangchen Technology's Leadership in N-PMI Innovation
As a pioneer in fine chemicals and polymer additives, Yangchen Technology leads the way in N-PMI technology:
A. Advanced Synthesis and Purification Technologies
Yangchen Technology utilizes a proprietary catalytic system and a closed-loop solvent recovery process to produce N-PMI with high purity (>99%) and low coloration. Our approach removes impurities that could accelerate polymer degradation, ensuring optimal performance in ABS formulations.
B. Custom Copolymer Design
We develop customized N-PMI-based copolymers, such as poly(N-phenylmaleimide-styrene-acrylonitrile-α-methylstyrene). These terpolymers exhibit high Tg values of 142.6°C, making them suitable for use as standalone high-temperature resins or as modifiers for ABS/PVC blends.
C. Scalable and Sustainable Production
Our facilities utilize continuous flow reactors and energy-efficient distillation to achieve high yields (≥95%) while minimizing waste. This scalability ensures reliable supply to our global customers, from pilot batches to industrial-scale orders.
4. Practical Applications: Advantages of N-PMI-Enhanced ABS
The thermal stability imparted by Yangchen Technology's N-PMI opens the door to demanding applications in the following industries:
- Automotive: Under-the-hood components, connector housings, and interior trim.
- Electronics: LED housings, power tool housings, and 3D printing consumables.
- Consumer Goods: Kitchen appliances, sanitary ware, and outdoor equipment.
ABS modified with Yangchen Technology's N-PMI retained >90% of its impact strength after 1000 hours at 110°C, >50% higher than conventional ABS.
Any questions,feel free to contact us!